Vinayaka Mission University
Vinayaka Missions University (VMU) is a pioneering and vibrant school offering a multi-social experience with an atmosphere checked by the ideal congruity of living in differing qualities.
Years1
UNIT - 01
PLANK`S QUANTUM THEORY - WAVE PARTICLE DUALITY - UNCERTAINTY PRINCIPLE -
OPERATOR AND OBSERVABLES - POSTULATES OF QUANTUM MECHANICS -
SCHRODINGER EQUATION - INTERPRETATION OF WAVE FUNCTION AND EXPECTATION
(EIGEN) VALUES.
UNIT - 02
ORTHOGONALITY AND NORMALIZATION OF WAVE FUNCTION - PRINCIPLE OF SUPER
POSITION - APPLICATION OF SCHRODINGER WAVE EQUATION TO PARTICLE IN ONE
DIMENSIONAL BOX - THREE DIMENSIONAL BOX.
UNIT - 03
SCHRODINGER EQUATION FOR HYDROGENATION - SEPARATION OF VARIABLES - PHIEQUATION
- THETA EQUATION AND RADIAL EQUATION - TOTAL WAVE FUNCTION.
UNIT - 04
QUANTUM NUMBERS AND THEIR SIGNIFICANCE - SHAPES OF ATOMIC ORBITALS -
ELECTRON SPIN AND PAULI EXCLUSION PRINCIPLE - POLY ELECTRONIC ATOMS.
UNIT - 05
INTER ELECTRON REPULSION AND ITS CONSEQUENCES ENERGY LEVELS IN POLY
ELECTRONIC ATOMS - R-S COUPLING - SPIN-ORBIT COUPLING - J-J COUPLING -
MICROSTATES AND THEIR CLASSIFICATION - TERM SYMBOLS.
UNIT - 06
NATURE OF COVALENT BOND - VALENCE BOND METHOD - CONCEPT OF RESONANCE
AND HYBRIDIZATION AND BOND ANGLES - APPLICATION TO SIMPLE MOLECULES -
MOLECULAR ORBITAL THEORY - GEOMETRICS OF THE ORBITALS - SYMMETRY AND
ANTI-SYMMETRY OF MOLECULAR ORBITALS - CONSTRUCTION OF MOLECULAR
ORBITALS IN DIATOMIC MOLECULES.
UNIT - 07
MOLECULAR ORBITALS IN POLAR MOLECULES - IONIC BONDING - LATTICE ENERGY -
BORN EQUATION AND ITS DERIVATION RADIUS RATIO RULES.
UNIT - 08
STRUCTURES OF SOME IONIC CRYSTALS - (SODIUM CHLORIDE - CESIUM CHLORIDE -
RUTILE - WURTZITE - FLOURITE) - HYDROGEN BONDING.
UNIT - 09
CO-ORDINATION CHEMISTRY OF TRANSITION METAL IONS - INTRODUCTION -
NOMENCLATURE - STABILITY CONSTRAINS OF COMPLEX AND THEIR DETERMINATION
(PH METRIC AND SPECTROPHOTOMETRIC METHODS) - FACTORS INFLUENCING
STABILITY.
Vinayaka Missions University,Directorate of Distance Education
Salem India
MASTER OF SCIENCE IN CHEMISTRY
1 Yr.
INORGANIC CHEMISTRY 1(2030201)
UNIT - 10
STABILIZATION OF UNUSUAL OXIDATION STATES - STEREOISOMERISM OF COORDINATION
COMPLEXES - ABSOLUTE CONFIGURATION OF COMPLEXES -
STREOSELETIVITY OF THE CONFORMATION F CHELATE RINGS.
UNIT - 11
BONDING IN COMPLEX - METAL - LIGAND BOND - V.B THEORY AND ITS LIMITATIONS -
CRYSTAL FIELD THEORY - SPLITTING OF D-ORBITALS - CFSE EVIDENCE FOR CFSE -
FACTOR AFFECTING SPLITTING -PETROCHEMICAL SERIES - SITE PREFERENCE -
LIMITATION OF CFT - LIGAND THEORY - M.O THEORY SIGMA AND PI-BONDING IN
COMPLEXES.
UNIT - 12
SPECTURAL AND MAGNETIC PROPERTIES OF COMPLEXES/TERM STATES FOR A D-ION
IN OCTAHEDRAL COMPLEXES - CHARACTERISTIC OF D-D TRANSITIONS - ENERGY LEVEL
DIAGRAMS OF ORGAL - SUGANO TAUNABLE - WEAK FIELD AND STRONG FIELD
CONCEPTS - JAHN TELLER DISTORTION - NEPHELAUXETIC EFFECT - MAGNETISM - DIA -
PARA MAGNETISM - SPIN ONLY MOMENTS OF DN-SYSTEMS.
AROMATICITY - INTRODUCTION - AROMATICITY OF BENZENOIDS AND HETEROCYCLIC
COMPOUNDS - NON-BENZENOID AROMATICS - ANNULENES. AZULENES AND
FERROCENES (SYNTHESIS NOT NECESSARY).
ANTIAROMATIC AND NON AROMATIC COMPOUNDS - KINETIC AND NONKINETIC
METHODS OF STUDY OF REACTION MECHANISMS - KINETIC METHODS - PRIMARY AND
SECONDARY KINETIC ISOTOPIC EFFECTS - NON-KINETIC METHODS - STUDY OF
REACTION - MECHANISM - STUDY OF INTERMEDIATES - ISOTOPIC LABELING -
STEREOCHEMICAL STUDIES AND CROSS OVER EXPERIMENTS - HAMMOND`S
POSTULATE - KINETIC AND THERMODYNAMIC CONTROL.
LINEAR FREE ENERGY RELATIONSHIP - HAMMETT EQUATION (TAFT EQUATION NOT
NECESSARY) - AROMATIC ELECTROPHILIC SUBSTITUTION - REACTIONS -
INTRODUCTION - MECHANISM OF ELECTROPHILIC SUBSTITUTION - REACTIONS SUCH
AS HALOGENATION - NITRATION
SULPHONATION AND FRIEDEL - CRAFTS ALKYLATION AND ACYLATION REACTIONS -
ORIENTATION AND REACTIVITY - ELECTROPHILIC SUBSTITUTION ON
MONOSUBSTITUTED AND DISUBSTITUTED BENZENES - TYPICAL REACTIONS SUCH AS
GATTERMANN REACTION GATTERMANN KOCH REACTION - RIMER TIEMANN REACTION -
KOLBE REACTION.
HOFMANN - MARTIUS AND JACOBSON`S REACTIONS - ALIPHATIC NUCLEEPHILIC
SUBSTITUTION REACTIONS & MECHANISMS - SNI, SN2, SNI MECHANISMS. FACTORS
AFFECTING NUCLEEPHILIC SUBSTITUTION REACTION - NATURE OF THE SUBSTRATE -
SOLVENT - NUCLEOPHILE AND LEAVING GROUP - NEIGHBOURING GROUP
PARTICIPATION - AMBIDENT NUCLEOPHILES AND AMBIDENT SUBSTRATES.
STEREOCHEMISTRY OF NUCLEOPHILIC SUBSTITUTION REACTIONS - SUBSTITUTION AT
VINYL CARBON ALLYLIC CARBON AND BRIDGE HEAD CARBON - TYPICAL
SUBSTITUTIONS SUCH AS VON BRAUN REACTION - CLAISEN CONDENSATION AND
HYDROLYSIS OF ESTERS.
ELIMINATION REACTIONS - EL, E2, EI, E1CB MECHANISMS - STEREOCHEMISTRY OF
ELIMINATION REACTIONS - ELIMINATION VS SUBSTITUTION - TYPICAL ELIMINATION
REACTIONS SUCH AS CHUGAEV REACTION - HOFMANN DEGRADATION - COPE
ELIMINATION - CARBENES AND NITRENES - STRUCTURE - GENERATION AND
REACTIONS.
ORGANIC CHEMISTRY 1(2030202)
FREE RADICAL REACTIONS - INTRODUCTION - STRUCTURE - STABILITY AND GEOMETRY
OF FREE RADICALS - GENERATIONS OF LONG LIVED AND SHORT LIVED FREE RADICALS
- CHARACTERISTICS OF FREE RADICAL REACTIONS - SUBSTITUTIONS - ADDITIONS AND
ELIMINATIONS - REARRANGEMENTS OF FREE RADICALS.
TYPICAL REACTIONS SUCH AS SANDMEYAR - GAMBERG - PECHMANN - ULLMAN -
PSCHORR AND HUNSDIECKER REACTIONS - 1. ADDITON REACTIONS : EELECTROPHILIC
AND NUCLEOPHILIC. ADDITION TO DOUBLE AND TRIPLE BENDS - HYDRATION.
HYDROXYLATION. MICHAEL ADDITION - HYDROBORATION AND APOXIDATION - 2.
ADDITION TO CARBONYL COMPOUNDS - MANNICH REACTION - DIECKMANN, STOBBE,
KNOVENAGEL, DARZEN, WITTIG, THORPE AND BENZOIN REACTIONS.
CONCERTED REACTIONS - PERICYCLIC REACTIONS - THE PERTURBATION THEORY OF
PERICYCLIC REACTIONS - THE ELECTROCYCLIC REACTIONS & SIGMATROPHIC
REACTIONS - THE WOODWARD - HOFMANN RULES - ORBITAL CORRELATION DIAGRAMS
- THE FRONTIER ORBITAL THEORY - CYCLOADDITIONS - DIEL`S ALDER REACTION. COPE
- CLAISEN AND DI-PI - METHANE REARRANGEMENTS.
STEREOISOMERISM - CONFIGURATIONAL & CONFORMATIONAL ISOMERISM -
INTRODUCTION - DEFINITION & CLASSIFICATION - MOLECULAR REPRESENTATION
(FISCHER PROJECTION, NEWMANN PROJECTION FORMULA) - BASIC REQUIREMENTS OF
OPTICAL ISOMERISM - OPTICAL ISOMERISM EXHIBITED BY A FEW NITROGEN AND
SULPHUR COMPOUNDS - THE ROLE OF NITROGEN INVERSION - CONFIGURATIONAL
NOMENCLATURE: D & L, R & S AND E & Z (OLEFINS) NOMENCLATURES.
CONFORMATIONS OF ACYCLIC AND CYCLIC MOLECULES - CONFORMATIONS OF
ETHANE AND 1, 2 DISUBSTITUTED ETHANES. CONFIGURATIONS AND CONFORMATIONS
SYMMETRY ELEMENTS AND SYMMETRY OPERATIONS - DEFINITION OF IDENTICAL AND
EQUIVALENT ELEMENTS - CONFIGURATIONS - SYMMETRY OPERATIONS AND
SYMMETRY ELEMENTS - ROTATION-AXIS OF SYMMETRY - REFLECTIONS-SYMMETRY
PLANES-INVERSION CENTER-IMPROPER ROTATIONS - ROTATION - REFLECTION AXISEFFECT
OF PERFORMING SUCCESSIVE OPERATIONS (COMMUTATIVE AND NON -
COMMUTATIVE) - INVERSE OPERATIONS.
GROUPS AND THEIR BASIC PROPERTIES - DEFINITION OF A GROUP - BASIC
PROPERTIES OF A GROUPDEFINITION OF ABELIAN GROUP-ISOMORPHIC GROUPSIMILARITY
TRANSFORMATION AND CLASSESGROUP - MULTIPLICATION TABLES -
SYMMETRY CLASSIFICATION OF MOLECULES INTO POINT GROUPS - (SCHOENFLIES
SYMBOL ONLY) DIFFERENCE BETWEEN POINT GROUP AND SPACE GROUP.
DEFINITION OF REDUCIBLE AND IRREDUCIBLE REPRESENTATIONS - IRREDUCIBLE
REPRESENTATIONS AS ORTHOGONAL VECTORS-DIRECT PRODUCT RULE - THE GREAT
ORTHOGONALITY THEOREM AND ITS CONSEQUENCES (STATEMENT ONLY PROOF NOT
NEEDED) - DETERMINATIONS OF THE CHARACTERS FOR IRREDUCIBLE
REPRESENTATION OF C2V AND C3V POINT GROUPS USING THE ORTHOGONALITY
THEOREMCALCULATION OF BINARY CO-ORDINATES IN THE CHARACTER TABLES FOR
C2V AND C3V POINT GROUPS - CALCULATION OF CHARACTER VALUES OF REDUCIBLE
REPRESENTATIONS PER UNSHIFTED ATOM FOR EACH TYPE OF SYMMETRY OPERATION
- DETERMINATION OF TOTAL CARTESIAN REPRESENTATION - DETERMINATION OF
DIRECT SUM FROM TOTAL CARTESIAN REPRESENTATION.
GROUP THEORY AND VIBRATIONAL SPECTROSCOPY - VIBRATIONAL MODES AS BASIS
FOR GOUP
REPRESENTATION - SYMMETRY SELECTION RULES FOR IR AND RAMAN SPECTRA
(MUTUAL EXCLUSION PRINCIPLE) - CLASSIFICATION OF VIBRATIONAL MODES - 1. THE
TIME-DEPENDENT AND TIME - INDEPENDENT SCHRODINGER EQUATIONS - BORN`S
INTERPRETATION OF THE WAVE FUNCTION. REQUIREMENTS OF THE ACCEPTABLE
WAVE FUNCTION.
CLASSIFICATION OF VIBRATIONAL MODES - 2. ALGEBRA OF OPERATORS. SUMS AND
PRODUCTS OF OPERATORS - COMMUTATOR. LINEAR OPERATORS - EIGEN FUNCTIONS
AND EIGEN VALUES - CORRESPONDENCE BETWEEN PHYSICAL QUANTITIES IN
CLASSICAL MECHANICS AND OPERATORS IN QUANTUM MECHANICS - HAMILTONIAN
OPERATOR - ANGULAR MOMENTUM OPERATOR -QUANTIZATION OF ANGULAR
MOMENTUM AND ITS SPATIAL ORIENTATION - AVERAGE (EXPECATION) VALUES.
PHYSICAL CHEMISTRY-I(2030203)
POSTULATES OF QUANTUM MECHANICS -1. PARTICLE IN A ONE-DIMENSIONAL BOX -
QUANTIZATION OF ENERGY - NORMALIZATION OF WAVE FUNCTION - ORTHOGONALITY
OF THE PARTICLE IN A ONE - DIMENSIONAL BOX WAVE FUNCTIONS - ILLUSTRATION OF
THE UNCERTAINTY PRINCIPLE AND CORRESPONDENCE PRINCIPLE WITH REFERENCE
TO THE PARTICLE IN A ONE DIMENSIONAL BOX - PARTICLE IN A THREE-DIMENSIONAL
BOX - SEPARATION OF VARIABLES - 2. SOLVING OF SCHRODINGER EQUATION FOR THE
ONE-DIMENSIONAL HARMONIC OSCILLATOR.
HARMONIC OSCILLATOR MODEL OF A DIATOMIC MOLECULE. - ILLUSTRATION OF THE
UNCERTAINTY
PRINCIPLE AND CORRESPONDENCE PRINCIPLE WITH REFERENCE TO HARMONIC
OSCILLATOR.
3. SOLVING OF SCHRODINGER EQUATION FOR A RIGID ROTOR - RIGID ROTOR MODEL
OF A DIATOMIC MOLECULE - 1. SCHRODINGER EQUATION FOR THE H-ATOM (OR H-LIKE
SPECIES) SEPARATION OF VARIABLES (SOLVING OF RADIAL EQUATION IS NOT NEEDED
BUT NATURE OF SOLUTION IS GIVEN) - ENERGY LEVELS - RADIAL FACTORS OF THE HATOM
WAVE FUNCTIONS -ORBITALS AND ORBITAL SHAPES - PROBABILITY DENSITY AND
RADIAL DISTRIBUTION FUNCTIONS - THE MOST PROBABLE DISTANCE OF THE H-ATOM
(OR H-LIKE SPECIES) 1S ELECTRON - 2. NEED FOR APPROXIMATION METHODS. THE
PERTURBATION THEORY (FIRST ORDER ONLY) - APPLICATION OF THE PERTURBATION
METHOD TO HE-ATOM.
THE VARIATION METHOD - APPLICATION OF VARIATION METHOD TO HE-ATOM -
THEMODYNAMICS AND NON-IDEAL SYSTEMS: CHEMICAL POTENTIAL AND THE
DEFINITION OF FUGACITY - DETERMINATION OF FUGACITY OF GASES BY GRAPHICAL
METHOD AND FROM EQUATIONS OF STATE - VARIATION OF FUGACITY WITH
TEMPERATURE - FUGACITY AND THE STANDARD
BASIC CONCEPTS - MONOMER - REPEAT UNITS - DEGREE OF POLYMERIZATION -
LINEAR - BRANCHED AND NETWORK POLYMERS - CONDENSATION POLYMERIZATION.
ADDITION POLYMERIZATION - FREE RADICAL - CATIONIC AND ANIONIC
POLYMERIZATION CONDITIONS - POLYMERIZATION IN HOMOGENEOUS AND
HETEROGENEOUS SYSTEMS.
CO-ORDINATION POLYMERIZATION - KINETICS - MONO AND BIMETALLIC MECHANISM OF
CO-ORDINATION POLYMERS - CO-POLYMERIZATION - BLOCK AND GRAFT COPOLYMERS.
KINETICS OF COPOLYMERIZATION - TYPES OF CO-OPERIZATION - EVALUATION OF
MONOMER - REACTIVITY RATIO - RATE OF CO-POLYMERIZATION.
MOLECULAR WEIGHT AND PROPERTIES OF POLYMERS - POLY DISPERSION - AVERAGE
MOLECULAR WEIGHT CONCEPT - NUMBER - WEIGHT AND VISCOSITY AVERAGE
MOLECULAR WEIGHTS - MEASUREMENT OF MOLECULAR WEIGHTS.
GEL PERMEATION CHROMATOGRAPHY - VISCOSITY - LIGHT SCATTERING - OSMOTIC
AND ULTRACENTRIFUGATION METHODS - POLYMER STRUCTURE AND PHYSICAL
PROPERTIES.
CRYSTALLINE MELTING POINT TEMPERATURE - THE GLASS TRANSITION TEMPERATURE
- DETERMINATION OF TG - RELATIONSHIP BETWEEN TM AND TG.
POLYMER PROCESSING - PLASTICS - ELASTOMERS AND FIBERS - COMPOUNDING
PROCESSING TECHNIQUES - CALENDARING - DIE CASTING - ROTATIONAL CASTING.
FILM CASTING - INJECTION MOULDING EXTRUSION MOULDING - THERMOFORMING -
FOAMING - REINFORCING AND FIBRE SPINNING.
PROPERTIES OF COMMERCIAL POLYMERS - POLYETHYLENE - POLYVINYL CHLORIDES -
POLYESTERS - PHENOLIC RESINS - EPOXY RESINS.
SILICONE POLYMERS FUNCTIONAL POLYMERS - FIRE RETARDING POLYMERS AND
ELECTRICALLY CONDUCTING POLYMERS.
POLYMER CHEMISTRY{MSC-CHEM}(2030204)
BIOMEDICAL POLYMERS - CONTACT LENS - DENTAL POLYMERS - ARTIFICIAL HEART -
KIDNEY -SKIN AND BLOOD CELLS.
INORGANIC CHEMISTRY - I
1.QUALITATIVE ANALYSIS QUALITATIVE ANALYSIS INVOLVES THE ANALYSIS OF A
MIXTURE CONTAINING FOUR CATIONS.
2.COLORIMETRIC ESTIMATIONS.
A.ESTIMATION OF IRON.
B.ESTIMATION OF NICKEL
C.ESTIMATION OF COPPER.
ORGANIC CHEMISTRY - I
1.PREPARATION OF P-BROMOACETANILIDE
2.PREPARATION OF P-BROMOANILINE
3.PREPARATION OF BENZOIN
4.PREPARATION OF NENZIL
5.PREPARATION OF S-BENZYL-ISO-THIRUONIUM CHLORIDE
6.PREPARATION OF BENZPINACOL
7.ORGANIC MIXTURE ANALYSIS
8.ANALYSIS IF ORGANIC MIXTURE CONTAIN TWO COMPONENTS INCLUDING
SEPARATION.
PHYSICAL CHEMISTRY - I
PARTITION OF CO-EFFICIENT
1.DETERMINATION OF PARTITION COEFFICIENT OF IODINE BETWEEN CORBON
TETRACHOLORIDE AND WATER.
2.DETERMINATION OF EQUILIBRIUM CONSTANT FOR THE REACTION I2 + I3
3.ESTIMATION OF I IONS FROM A KNOWLEDGE OF THE EQUILIBRIUM CONSTANT OF THE
ABOVE REACTION.CONDUCTIVITY MEASUREMENTS
4.DETERMINATION OF CELL CONSTANT OF A CONDUCTIVITY CELL.
5.A STUDY OF VARIATION OF EQUIVALENT CONDUCTANCE OF A STRONG ELECTROLYTE
WITH CONCENTRATION.
6.DETERMINATION OF DISSOCIATION CONSTANT OF A WEAK ACID.
7.CONDUCTOMETRIC TITRATIONS :
A.MIXTURE OF HCL AND ACETIC ACID VS NAOH.
B.AMMONIUM CHLORIDE VS NAOH.
C.A SOLUTION CONTAINING BA2+ IONS VS A SOLUTION CONTAINING SO42- .
PHASE RULE
8.CONSTRUCTION OF PHASE DIAGRAM FOR DIPHENYL-NAPHTHALENE SYSTEM.
9.DETERMINATION OF COMPOSITION OF A MIXTURE OF DIPHENYL AND NAPHTHALENE.
DETERMINATION OF MOLECULAR WEIGHTS
10.DETERMINATION OF MOLECULAR WEIGHT BY CRYOSCOPIC METHOD USING
PRACTICAL(MSC-CHEM)(2030205)
BENZENE AS SOLVENT.
11.DETERMINATION OF MOLECULAR WEIGHT BY CRYOCOPIC METHOD USING WATER
AS SOLVENT.
12.DETERMINATION OF MOLECULAR WEIGHTS BY RAST`S METHOD.
UV AND IR SPECTROSCOPY - ULTRAVIOLET - VISIBLE SPECTROSCOPY - TYPES OF
ELECTRONIC TRANSITIONS - CHROMOPHORES AND AUXOCHROMS - FACTORS
INFLUENCING POSITION AND INTENSITY OF ABSORPTION BANDS.
ABSORPTION SPECTRA OF DIENES - PLOYENES - ALPHA - BHETA - UNSATURED
CARBONY 1 COMPOUNDS - WOODWARD - FIESER RULES - IR SPECTROSCOPY -
VINRATIONAL FREQUENCIES - FACTORS AFFECTING THEM - IDENTIFICATION OF
FUNCTIONAL GROUPS.
INTRA AND INTER MOLECULAR HYDROGEN BONDING - FINGER PRINT REGION - FAR IT
REGION - METAL LIGAND STRETCHING VIBRATIONS.
1H NMR SPECTRA - NUCLEAR SPIN - MAGNETIC MOMENTS OF A NUCLEUS - NUCLEAR
SPIN ENERGY LEVELS IN THE PRESENCE OF MAGNETIC FIELDS.
SPIN ENERGY LEVELS IN THE PRESENCE OF MAGNETIC FIELDS
13C NMR - TWO DIMENSIONAL NMR SPECTROSCOPY - 13C NMR - PROTON DECOUPLED
AND OFF-RESONANCE - 13C NMR SPECTRA - FACTORS AFFECTING 13C CHEMICAL
SHIFTS - 13C NMR SPECTRA OF SIMPLE ORGANIC MOLECULES.
USE OF INEPT AND DEPT METHODS IN ASSIGNING 13C SIGNALS - BASIC PRINCIPLES OF
TWO DIMENSIONAL NMR SPECTROSCOPY - HOMOCOSY - HETCOSY - NOESY.
PRINCIPLES - MEASUREMENT TECHNIQUES (EI, CI, FD FAB, SIMS) - PRESENTATION OF
SPECTRA DATA.
MOLECULAR IONS - ISOTOPE IONS.
FRAGMENT IONS OF ODD AND EVEN ELECTRON TYPES - REARRANGEMENT IONS -
FACTORS AFFECTING FRAGMENTATION PATTERNS - MC.LAFFERTY REARRANGEMENT.
IDENTIFICATION OF ORGANIC COMPOUNDS USING UV - IR - NMR SPECTROSCOPY.
SPECTROSCOPY AND SPECTROMETER(2030105)
MASS SPECTROMETRY - PROBLEMS.
Years2
ELECTROPHILIC AND NUCLEOPHILIC ADDITIONS - ADDITION TO CONJUGATED SYSTEMS
- ORIENTATION AND REACTIVITY - ADDITION OF HALOGEN AND NITROSYL CHLORIDE TO
OLEFINS - HYDRATION OF OLEFINS AND ACETYLENES.
HYDROXYLATION EPOXYDATION - MICHEL ADDITION - 1, 3 DIOPOLAR ADDITION -
CARBONS AND THEIR ADDITIONS - DIES-ALDER REACTIONS.
MECHANISM AND REACTIVITY - MANNICH - STOOBE - DARZEN GLYCIDIC EATER
CONDENSATION - BENZOIN CONDENSATION - PETERSON OLEFINATION (SILYL WITTING
REACTION).
STRECKER SYNTHESIS - WITTING-HORNER REACTIONS - PERKIN`S REACTIONS -
THORPE - RITTER REACTIONS - PRINS REACTIONS.
E1, E2, E1CB MECHANISMS - ORIENTATION OF THE DOUBLE BOND - HOFMANN AND
SAYTZEFF RULE - COMPETITION BETWEEN CLIMINATION AND SUBSTITUTION.
DEHYDRATION AND DEHYDRO HALOGENATION REACTIONS - STEREOCHEMISTRY OF E2
ELIMINATIONS IN CYCLOHEXANE RING SYSTEMS - MECHANISM OF PYROLYTIC
ELIMINATIONS - CHUGAEV REACTION AND COPE ELIMINATION.
A DETAILED STUDY OF THE MECHANISM OF THE FOLLOWING REARRANGEMENTS -
NUCLEOPHILIC - ELECTROPHILIC AND FREE RADICAL REARRANGEMENTS - MEMORY
EFFECTS -MIGRATORY APTITUDES - PINACOL-PINACOLONE.
WAGNER-MEERWIN REARRANGEMENTS - DIENONE-PHENOL - BAEYER-VILLIGER -
WOLFF STEVENS AND VON-RICHTER (A FEW EXAMPLES IN EACH REARRANGEMENT
ARE TO BE USED) REARRANGEMENTS INVOLVING NITRENES - HOFMANN - CURTIUS -
LOSSEN AND BECKMANN.
STUDY OF THE FOLLOWING OXIDATION REACTIONS WITH MECHANISM - OXIDATION OF
ALCOHOLS BY CRO3 - DMSO ALONE - DMSO IN COMBINATION WITH DC.
ACETIC ANHYDRIDE - OXIDATION OF ARYL METHANE - OXIDATION OF METHYLENE
ALPHA TO CARBONYL - ALLYLIC OXIDATION OF OLEFINS.
2 Yr.
ORGANIC CHEMISTRY-II(2030207)
OXIDATIVE CLEAVAGE OF GLYCOLS - OXIDATIVE CLEAVAGE OF GLYCOLS - OXIDATIVE
CLEAVAGE OF DOUBLE BY OZONOLYSIS.
STUDY OF THE FOLLOWING REDUCTION REACTIONS WITH MECHANISM - REDUCTION
OF CARBONYL COMPOUNDS BY HYDRIDES - SELECTIVITY IN REDUCTION OF 4-TERBUTYL
CYCLOHEXANONE - CLEMMENSEN AND WOLFF KISHNER REDUCTIONS - BIRCH
REDUCTION - MPV REDUCTION.
CRYSTAL FIELD THEORY - SPLITTING OF D-ORBITALS UNDER VARIOUS GEOMETRIES -
FACTORS AFFECTING SPLITTING - CFSE AND EVIDENCES FOR CFSE (STRUCTURAL AND
THERMODYNAMIC EFFECTS).
SPECTROCHEMICAL SERIES - JAHN TELLER DISTORTION - SITE PREFERENCES -
LIMITATIONS OF CFT - EVIDENCE FOR METAL-LIGAND OVERLAP - MOLECULAR ORBITAL
THEORY AND ENERGY LEVEL DIAGRAMS - CONCEPT OF WEAK AND STRONG FIELDS -
SIGMA AND BONDING IN COMPLEX - NEPHELAUXETIC EFFECT - MAGNETIC PROPERTIES
OF COMPLEXES.
TERM SYMBOLS FOR DN IONS - CHARACTERISTICS OF D-D TRANSITIONS AND
SELECTION RULES - WEAK AND STRONG FIELD LIMITS - ENERGY LEVEL DIAGRAMS.
ORGAL AND TANABE-SUGANO DIAGRAMS - EFFECT OF DISTORTION AND SPIN ORBITAL
COUPLING ON SPECTRA.
STRUCTURE OF SOLIDS - COMPARISON OF X-RAY DIFFRACTION - NEUTRON AND
ELECTRON DIFFRACTION - STRUCTURE OF NIAS - CDL2 - PERVOSKITE - SPINELS AND
INVERSE SPINELESS - DEFECTS IN SOLIDS - POINT DEFECTS.
LINE EFFECTS AND SURFACE DEFECTS - NON-STOICHIOMETRIC COMPOUNDS - USE OF
X-RAY POWDER DATA IN IDENTIFYING INORGANIC CRYSTALLINE SOLIDS - DETAILS FOR
CUBIC SYSTEMS.
ELECTRICAL PROPERTIES OF SOLIDS - BAND THEORY - SEMICONDUCTOR - SUPER
CONDUCTOR - SOLID STATE ELECTROLYTES - MAGNETIC PROPERTIES - DIA - PARA -
FERRO - ANTIFERRO AND FERRIMAGNETISM.
HYSTERISIS - FERRITES - GARNETS - OPTICAL PROPERTIES - SOLID STATE LASERS AND
INORGANIC PHOSPHORS - REACTIONS IN SOLID STATE AND PHASE TRANSITIONS -
DIFFUSION COEFFICIENT.
DIFFUSION MECHANISM - VACANCY AND INTERSTITIAL DIFFUSIONS - FORMATION OF
SPINELS - SOLID SOLUTION - ORDER-DISORDER TRANSFORMATIONS AND SUPER
STRUCTURE.
INORGANIC CHEMISTRY-II(2030208)
CHROMATOGRAPHY - GAS - LIQUID CHROMATOGRAPHY - PRINCIPLE - RETENTION
VOLUMES - CARRIER GAS - COLUMNS - PREPARATIONS - STATIONARY PHASE -
DETECTORS.
THERMAL CONDUCTIVITY - IONIZATION - ELECTRON CAPTURES APPLICATIONS OF GLC.
HIGH PERFORMANCE LIQUID CHROMATOGRAPHY - SCOPE - COLUMN EFFICIENCY -
INSTRUMENTATION - PUMPING SYSTEMS - COLUMNS - COLUMN PACKING DETECTORS -
APPLICATIONS.
CHEMICAL KINTEICS - II
1.1CATALYSIS BY ENZYMES, KINETICS OF SINGLE SUBSTRATE ENZYME CATALYZED
REACTIONS, EFFECT OF SUBSTRATE CONCENTRATION. PH AND TEMPERATURE OF
ENZYME CATALYZED REACTIONS, INHIBITION OF ENZYME CATALYZED REACTIONS.
1.2KINETICS OF COMPLEX REACTIONS, REVERSIBLE REACTIONS, CONSECUTIVE
REACTIONS, PARALLEL REACTIONS CHAIN REACTIONS, GENERAL TREATMENT OF
CHAIN REACTION, CHAIN LENGTH, RICE HERZFED MECHANISM, EXPLOSION LIMITS.
2.1STUDY OF KINETICS OF SURFACE REACTIONS
PHYSICAL AND CHEMICAL ABSORPTION, ADSORPTION , ISOTHERMS, TYPES OF
ADSORPTION ISOTHERMS, LONGMUIR ADSORPTION ISOTHERM. BET THEORY FOR
MULTILAYER ADSORPTION, APPLICATION OF TRANSITION STATE THEORY TO
ADSORPTION, MEASUREMENT OF SURFACE AREA, CATALYSIS BY METALS AND
SEMICONDUCTOR OXIDES. MECHANISMS OF HETEROGENEOUS CATALYTIC
REACTIONS, THE ADSORPTION COEFFICIENT AND ITS SIGNIFICANCE
2.2STUDY OF FAST REACTIONS
RELAXATION METHODS, TEMPERATURE AND PRESSURE JUMP METHODS, STOPPED
FLOW AND FLASH PHOTOLYSIS METHODS.
THERMODYNAMICS - II
3.1OBJECTIVES OF STATISTICAL THERMODYNAMICS, CONCEPT OF THERMODYNAMIC
AND MATHEMATICAL PROBABILITIES, DISTRIBUTION OF DISTINGUISHABLE AND
INDISTINGUISHABLE PARTICLES. MAXWELL-BOLTZMANN, FERMI_DIRAC, BOSE-EINSTEIN
STATISTICS, COMPARISON AND APPLICATIONS, MODES OF CONTRIBUTION TO ENERGY,
RADIATION LAW.
3.2PARTITION FUNCTION, EVALUATION OF TRANSLATIONAL VIBRATIONAL AND
ROTATIONAL PARTITION FUNCTIONS FOR MONO, DIATOMIC AND POLYATOMIC
IDEALGASES, THERMODYNAMIC FUNCTIONS IN TERMS OF PARTITION FUNCTIONS,
CALCULATION OF EQUILIBRIUM CONSTANTS FROM PARTITION FUNCTIONS (ISOTOPE
EXCHANGE AND DISSOCIATION OF DIATOMIC MOLECULES), APPLICATION OF PARTITION
FUNCTIONS TO HEAT CAPACITIES OF IDEAL GASES, HEAT CAPACITY OF SOLIDS
(EISNSTEIN AND DEBYE MODELS).
EXPERIMENT RESULTS OF BLACK BODY RADIATION - PHOTO EFFECT , COMPTON
EFFECT, QUANTUM MECHANICAL POSTULATES, THE SCHORDINGER EQUATION - THE
PARTICLE IN A BOX (ONE, TWO AND THREE DIMENSIONAL SYSTEMS), THE HARMONIC
WAVE PARTICLE DUALITY - DE BROGILE EQUATION, UNCERTAINTY PRINCIPLE.
SCHRODINGER EQUATION FOR THE RIGID ROTATOR, THE HYDROGEN ATOM - SETTING
PHYSICAL CHEMISTRY-II(2030209)
UP THE SCHRODINGER, ARRIVING SOLUTION FOR ENERGY AND WAVE FUNCTIONS.
THE ORIGIN OF QUANTUM NUMBERS AND THEIR PHYSICAL SIGNIFICANCE.
CONFORMATIONAL ANALYSIS - CONFORMATION AND STEREOCHEMISTRY OF CIS AND
TRANS DECALINS, CONFORMATIONS OF SOME SIMPLE 1,2 DISUBSTITUTED
DERIVATIVES - ETHYLENE CHLOROHYDRIN AND ETHYLENE GLYCOL, CONFORMATIONAL
ANALYSIS AND STEREOCHEMICAL FEATURES OF DISUBTITUTED CYCLOHEXANES -
OXIDATION AND ACYLATION OF CYCLOHEXANOLS, REDUCTION OF CYCLOHEXANONES,
ESTERIFICATION AND HYDROLYSIS OF CYCLOHEXANOLS, CARBOXYLIC ACID
DERIVATIVES. GEOMETRIC ISOMERISM - E AND Z NOMENCLATURE OF OLEFINS
CONTAINING ONE AND MORE THAN ONE BOND.
STEREOCHEMISTRY - HOMOTOPIC, ENANTIOTOPIC, DIASTEREOTOPIC H ATOMS,
GROUPS, AND FACES. MOLECULES WITH MORE THAN ONE ASYMMETRIC CENTRE -
EXAMPLES ERYTHRO AND THREO COMPOUNDS. FISCHER PROJECTION, NEWMANNN
PROJECTION. SAW - HORSE FORMULA AND THEIR INTER CONVERSION S FOR ORGANIC
MOLECULES. STEREO SPECIFIC AND STEREO SELECTIVE SYNTHESIS, ASYMMETRIC
SYNTHESIS -CRAM`S RULE. OPTICAL ACTIVITY IN THE ABSENCE OF CHIRAL CARBON -
BIPHENYLS, ALLENES AND SPIRANES - R AND S NOTATIONS. CHIRALITY DUE TO
HELICAL SHAPE, TRANS CYCLOOCTANE, CYCLONONENE.
STRUCTURE AND BONDING - VANDERWAALS BONDING - HYDROGEN BONDING. A
GENERALIZED ACID-BASE CONCEPT, MEASURES OF ACID-BASE STRENGTH.
POLYACIDS, ISOPOLYCAIDS OF V,CR, MO AND W. HETERO POLYACIDS OF MO AND W
(ONLY STRUCTURAL ASPECTS) INORGANIC POLYMERS-SILICATES-STRUCTURE,
PROPERTIES, CORRELATION AND APPLICATION. MOLECULAR SIEVES, POLYSULPHURNITROGEN
COMPOUNDS AND POLYORGANOPHOSPHOZENES.
BORON COMPOUNDS AND CLUSTERS- BORON HYDRIDES, POLYHYDRAL BORANES,
HYDROBORATE IONS-A STUDY OF PREPARATION. PROPERTIES AND STRUCTURE.
CARBORANES TYPES SUCH AS CLOSO AND NIDO-PREPARATION, PROPERTIES AND
STRUCTURE. METALLOCARBORANES- A GENERAL STUDY. METAL CLUSTERSCHEMISTRY
OF LOW MOLECULARITY METAL CLUSTERS ONLY, MULTIPLE METAL-METAL
BONDS.
CHEMICAL KINETICS- THEORIES, ANALYSIS AND INTERPRETATION OF KINETIC DATA,
RATE AND MECHANISM OF REACTIONS- TYPICAL EXAMPLES. THEORIES OF REACTION
RATES- ARRHENIUS THEORY-EFFECT OF TEMPERATURE ON REACTION RATES, HARD
SPHERE - COLLISION THEORY OF REACTION RATES, MOLECULAR BEAMS, COLLISION
CROSS SECTION, EFFECTIVENESS OF COLLISIONS, PROBABILITY FACTORS,
TRANSITION STATE THEORY OF REACTION RATES, HARD SPHERE- COLLISION THEORY
OF REACTION RATES, MOLECULAR BEAMS, COLLISION CROSS SECTION,
EFFECTIVENESS OF COLLISIONS, PROBABILITY FACTORS, TRANSITION STATE THEORY
GENERAL CHEMISTRY-II(2030210)
OF RATES, POTENTIAL ENERGY SURFACES, PARTITION FUNCTIONS AND ACTIVATED
COMPLEX, ERYING EQUATION, ESTIMATION OF FREE ENERGY, ENERGY, ENTHALPY AND
GRAVIMETRIC ANALYSIS - FORMATION AND TREATMENT OF PRECIPITATES - COPRECIPITATION
- POST PRECIPITATION AND ABSORPTION PHENOMENA -
HOMOGENEOUS PRECIPITATION - MAKING - SPECIFIC AND SELECTIVE PRECIPITATIONS.
VOLUMETRIC ANALYSIS - THEORY AND PRINCIPLES OF ACID BASE REDOX COMPLEX
METRIC AND PRECIPITATION TITRATIONS - TITRATIONS IN NON-AQUEOUS SOLVENTS
EQUILIBRIA IN SOLUTIONS OF MONO AND POLYPROTIC ACIDS - AMINO ACID TITRATIONS
- TREATMENTS OF ANALYTICAL DATA.
NATURE OF QUANTITATIVE MEASUREMENTS AND TREATMENT OF DATA ACCURACY
AND PRECISION - TYPES OF ERRORS - SIGNIFICANT FIGURES - MEAN AND STANDARD
DEVIATION - REJECTION OF DATA - COMPARISON OF RESULTS - F AND T TESTS -
REGRESSION AND CORRELATION.
INSTRUMENTAL METHODS OF ANALYSIS - INSTRUMENTATION - INSTRUMENTATION IN
UV - IR - RAMAN - NMR AND EPR SPECTRAL METHODS.
ATOMIC ABSORPTION SPECTROSCOPY - PRINCIPLES AND APPLICATIONS.
ELECTRO ANALYTICAL METHODS - PRINCIPLES AND APPLICATIONS OF
POTENTIOMETRY - CONDUCTOMETRY - ELECTRO GRAVIMETRY - COULMETRY -
POLAROGRAPHY AND CYCLIC VOLTAMETRY - AMPEROMETRIC TITRATIONS.
PRINCIPLES AND APPLICATIONS OF THERMO GRAVIMETRIC AND DIFFERENTIAL
THERMAL ANALYSIS.
CHROMATOGRAPHIC METHODS OF ANALYSIS - THEORY OF CHROMATOGRAPHY -
DISTRIBUTION EQUILIBRIA - RATE OF TRAVEL - RETENTION TIME - RETENTION VOLUME -
RELATIVE RETENTION - PLATE THEORY - RATE THEORY - RESOLUTION.
PRINCIPLES OF COLUMN - PAPER - VAPOR - THIN LAYER AND ION EXCHANGE
CHROMATOGRAPHIC METHODS - EXAMPLES FOR SEPARATION AND PURIFICATION
USING THE ABOVE METHODS.
ZONE ELECTROPHORESIS AND HIGH PERFORMANCE LIQUID CHROMATOGRAPHY.
ANALYTICAL CHEMISTRY(MSC-CHEM)(2030211)
ELECTRONICS - ELECTRICAL FUNDAMENTALS - RESISTANCE - CAPACITANCE -
INDUCTANCE IMPEDANCE - RESONANCE - ELECTRICAL CIRCUITS - FILTERS - SEMI
CONDUCTORS - DEVICES - DIODES - TRANSISTORS - OPERATIONAL AMPLIFIERS -
RECTIFIERS - CIRCUITS FOR POLAROGRAPHY - COULOMETRY AND POTENTIOMETRY -
CHEMICAL INSTRUMENTATION ORIGIN AND TYPE OF NOISE OPTIMIZATION OF SIGNAL
TO NOISE RATIO.
COMPUTER PROGRAMMING - INPUT AND OUTPUT STATEMENTS - TRANSFER AND
CONTROL STATEMENTS - PROGRAMMING IN BASIC ONLY FOR CALCULATION OF
EQUILIBRIUM CONSTANTS - PH OF BUFFER - POTENTIOMETRIC TITRATIONS AND
STANDARD DEVIATION - MS WORD - MS-EXCEL AND INTERNET USAGE - MS POWER
POINT.
PART - I:
SEMIMICRO QUALITATIVE ANALYSIS OF MIXTURES CONTAINING TWO COMMON AND
TWO RAE CATIONS. THE FOLLOWING ARE THE CARE TO BE INCLUDED : W, TI, MO, TC,
SC, CC, TH, BE, ZR, V, U AND LI.
PART - II:
A.COLORIMETRIC ANALYSIS : VISUAL AND PHOTOMETRIC : DETERMINATION OF IRON,
NICKET, MANGANESE AND COPPER.
B.PREPARATION OF THE FOLLOWING :
I.POTASSIUM TRIOXALATOALUMINATE (III) TRIHUDRATE
II.TRISTHIOUREACOPPER (I) CHLORIDE
III.POTASSIUM TRIOXALATOCHROMATE (III) TRIHYDRATE
IV.SODIUM BIS (THIOSULPHATO) CUPRATE (I)
V.TETRAMMINECOPPER (II) SULPHATE
VI.POTASSIUM TETRACHLOROCUPRATE (II)
C.SEPARATION OF MIXTURE OF TWO METAL IONS BY PAPER CHROMATOGRAPHY.
PRACTICAL IV: INORGANIC CHEMISTRY II(2030212)
1.IDENTIFICATION OF COMPONENTS IN A TWO COMPONENT MIXTURE AND
PREPARATION OF THEIR DERIVATIVES. DETERMINATION OF BOILING POINT/MELTING
POINT FOR COMPONENTS AND MELTING POINT FOR THEIR DERIVATIVES.
II. PREPARATION :
1.BETA NAPHTYL METHL ETHER FORM BETA NAPHTHOL
2.S- BENZYL ISOTHIURONIUM CHLORIDE FROM BENZYCLHROIDE
3.BETA GLUCOSE PENTA ACETATE FROM GLUCOSE
4.ORTHO-BENZOYL BENZOIC ACID FROM PHTHALIC ANHYDRIDE
5.RESACETOPHENONE FROM RESORCINOL
6.PARA-NITROBENZOIC ACID FROM PARA NITROTOLUNE
7.META-NITROANILLINE FROM META DINITROBENZENE
8.METHYL ORANGE FROM SULPHANILLIC ACID
9.ANTHRAQUINONE FROM ANTRACENE
10.BENZYHYDROL FROM BENOPHENONE
PRACTICAL V: ORGANIC CHEMISTRY II(2030213)
EXPERIMENTS IN CHEMICAL KINETICS, PHASE RULE, CHEMICAL EQUILIBRIUM AND
CONDUCTIVITY MEASUREMENTS:
DETAILED OF EXPERIMENTS: TYPICAL LIST OF POSSIBLE EXPERIMENTS ARE GIVEN.
EXPERIMENTS OF SIMILAR NATURE AND OTHER EXPERIMENTS MAY ALSO BE GIVEN.
THE LIST GIVEN IS ONLY A GUIDELINE. A MINIMUM OF 15 EXPERIMENTS HAVE TO BE
PERFORMED IN A YEAR.
1.STUDY THE KINETICS OF ACID HYDROLYSIS OF AN ESTER, DETERMINATION OF THE
TEMPERATURE COEFFICIENT OF THE REACTION AND DETERMINATION OF THE
ACTIVATION ENERGY OF THE HYDROLYSIS OF ETHYLACETATE.
2.STUDY THE KINETICS OF THE REACTION BETWEEN ACETONE AND IODINE IN ACIDIC
MEDIUM BY HALF LIFE METHOD AND DETERMINE THE ORDER WITH RESPECT TO IODINE
AND ACETONE.
3.STUDY OF THE SAPONIFICATION OF ETHYLACETATE BY SODIUM HYDROXIDE
CONDUCTOMETRICALLY AND DETERMINE THE ORDER OF THE REACTION.
4.DETERMINATION OF DISSOCIATION OF ETHYLACETATE BY SODIUM HYDROXIDE
CONDUCTOMERTICALLY AND DETERMINE THE ORDER THE REACTION.
5.STUDY THE PHASE DIAGRAM FOR M-TOLUIDINE AND GLYCERIN SYSTEM.
6.CONSTRUCTION OF PHASE DIAGRAM FOR A SIMPLE BINARY SYSTEM (NAPHTHALENEPHENANTHRENE
AND BENZOPHENONE-DIPHENYLAMINE).
7.CONSTRUCTION OF THE PHASE DIAGRAM OF THE THREE COMPONENT OF PARTIALLY
IMMISCIBLE LIQUID SYSTEMS (DMSO-WATER-BENZENE; WATER-BENZENE-ACETIC ACID;
ETHYL ALCOHOL-BENZENE-WATER; ACETONE-CHLOROFORM-WATER; CHLOROFORMACETIC
ACID-WATER).
8.DETERMINATION OF THE EQUILIBRIUM CONSTANT OF THE REACTION BETWEEN
IODINE AND PARTITION METHOD.
9.DETERMINATION OF EQUIVALENT CONDUCTANCE OF A WEAK ACID AT DIFFERENT
CONCENTRATIONS AND VERIFY OSTWALD`S DILUTION LAW AND CALCULATION OF THE
DISSOCIATION CONSTANT OF THE ACID.
10.DETERMINATION OF EQUIVELANT CONDUCTIVITY OF A STRONG ELECTROLYTE AT
DIFFERENT CONCENTRATIONS AND EXAMINE THE VALIDITY OF THE ONSAGAR`S
THEORY AS LIMITING LAW AT HIGH DILUTIONS.
11.CONDUCTOMETRIC TITRATIONS OF A MIXTURE OF HCL AND CH3COOH AGAINST
SODIUM HYDROXIDE.
12.COMPARE THE RELATIVE STRENGTH OF ACETIC ACID AND MONOCHLOROACETIC
ACID BY CONDUCTIVITY METHOD.
PRACTICAL VI: PHYSICAL CHEMISTRY II(2030214)
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